Johnson, Brian P., Almstätter, Stefan, Dielmann, Fabian, Bodensteiner, Michael and Scheer, Manfred (2010) Synthesis and Reactivity of Low-Valent Group 14 Element Compounds. ZAAC 636 (7), pp. 1275-1285.
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Other URL: http://onlinelibrary.wiley.com/doi/10.1002/zaac.201000029/full
Abstract
The tetravalent germanium and tin compounds of the general formulae Ph*EX3 (Ph* = C6H3Trip-2,6, Trip = C6H2iPr3-2,4,6; E = Sn, X = Cl (1a), Br (1b); E = Ge, X = Cl (2)) are synthesized by reaction of Ph*Li·OEt2 with EX4. The subsequent reaction of 1a,b with LiP(SiMe3)2 leads to Ph*EP(SiMe3)2 (E = Sn (3), Ge (4)) and the diphosphane (Me3Si)2PP(SiMe3)2 by a redox reaction. In an alternative ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | June 2010 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number: |
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| Keywords: | Germanium; Tin; Phosphorus; Multiple bonding; Density functional calculations | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Unknown | ||||
| Created at the University of Regensburg: | Unknown | ||||
| Item ID: | 19850 |
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