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Coordination Chemistry of [Cp*Fe(η5-P3C2tBu2)] (Cp* =η5-C5Me5) with Copper(I) Halides - Formation of Oligomeric and Polymeric Compounds

Schindler, Andrea ; Balázs, Gábor ; Zabel, Manfred ; Gröger, Christian ; Kalbitzer, Hans Robert ; Scheer, Manfred



Abstract

The reaction of the 1,2,4-triphosphaferrocene [Cp*Fe(eta(5)-P(3)C(2)tBu(2))] (1) with CuX (X = Cl, Br, I) in a 1:1 stoichiometric ratio leads to the formation of the oligomeric compounds [{Cu(mu-X)}(6)(mu(6)-X)Cu(MeCN)(3){mu,eta(2)-(CP*Fe(eta(5)-P(3)C(2)tBu(2)))}(2){mu(3),eta(3)-(CP*Fe*(eta(5)-P(3)C(2)tBu(2)))}] (X = Cl (2), Br (3)) and ...

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