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Coordination Chemistry of [Cp*Fe(η5-P3C2tBu2)] (Cp* =η5-C5Me5) with Copper(I) Halides - Formation of Oligomeric and Polymeric Compounds

Schindler, Andrea ; Balázs, Gábor ; Zabel, Manfred ; Gröger, Christian ; Kalbitzer, Hans Robert ; Scheer, Manfred


The reaction of the 1,2,4-triphosphaferrocene [Cp*Fe(η5-P3C2tBu2)] (1) with CuX (X = Cl, Br, I) in a 1:1 stoichiometric ratio leads to the formation of the oligomeric compounds [{Cu(μ-X)}6(μ6-X)Cu(MeCN)3{μ,η2-(Cp*Fe(η5-P3C2tBu2))}2{μ3,η3-(Cp*Fe(η5-P3C2tBu2))}] (X = Cl (2), Br (3)) and [{Cu(μ-I)}3{Cu(μ3-I)}3Cu(μ6-I){μ,η2-(Cp*Fe(η5-P3C2tBu2))}3{η1-(Cp*Fe(η5-P3C2tBu2))}] (4) revealing Cu(I) halide ...


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