Schindler, Andrea, Balázs, Gábor, Zabel, Manfred, Gröger, Christian, Kalbitzer, Hans Robert and Scheer, Manfred (2010) Coordination Chemistry of [Cp*Fe(η5-P3C2tBu2)] (Cp* =η5-C5Me5) with Copper(I) Halides - Formation of Oligomeric and Polymeric Compounds. Comptes Rendus Chimie 13 (8-9), pp. 1241-1248.
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Abstract
The reaction of the 1,2,4-triphosphaferrocene [Cp*Fe(η5-P3C2tBu2)] (1) with CuX (X = Cl, Br, I) in a 1:1 stoichiometric ratio leads to the formation of the oligomeric compounds [{Cu(μ-X)}6(μ6-X)Cu(MeCN)3{μ,η2-(Cp*Fe(η5-P3C2tBu2))}2{μ3,η3-(Cp*Fe(η5-P3C2tBu2))}] (X = Cl (2), Br (3)) and [{Cu(μ-I)}3{Cu(μ3-I)}3Cu(μ6-I){μ,η2-(Cp*Fe(η5-P3C2tBu2))}3{η1-(Cp*Fe(η5-P3C2tBu2))}] (4) revealing Cu(I) halide ...

Export bibliographical data
Item type: | Article | ||||
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Date: | September 2010 | ||||
Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
Identification Number: |
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Keywords: | P ligands; Copper(I) halides; Triphosphaferrocenes; Iron; Solid-state structures; Supramolecular chemistry | ||||
Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
Status: | Published | ||||
Refereed: | Yes, this version has been refereed | ||||
Created at the University of Regensburg: | Yes | ||||
Item ID: | 19880 |