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A New Building Block for Organometallic-Inorganic Hybrid Polymers: The Mixed Group 15/16 Element Ligand Complex [Cp*2Mo2(µ,η2:2-PSe)2(µ-Se)] (Cp* =η5-C5Me5)

Bodensteiner, Michael ; Dušek, Michal ; Kubicki, Marek M. ; Pronold, Michael ; Scheer, Manfred ; Wachter, Joachim ; Zabel, Manfred


The synthesis and spectroscopic characterization of [Cp*2Mo2P2Se3] (1; Cp* = C5Me5) and its use as a molecular building block in the formation of copper(I) halide polymers is described. The reaction of 1 in CH2Cl2 with 2 equiv. of CuBr and CuI in CH3CN under diffusion conditions gave [(Cp*2Mo2P2Se3)2(CuBr)2] (2) and [(Cp*2Mo2P2Se3)(CuX)3(CH3CN)]n (X = I; 3/4), respectively. The structure of 2 is ...


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