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Organometallic Nano-sized Capsule Consisting of cyclo-P5 Units and Cu(I) Ions

Welsch, Stefan, Gröger, Christian, Sierka, Marek and Scheer, Manfred (2011) Organometallic Nano-sized Capsule Consisting of cyclo-P5 Units and Cu(I) Ions. Angewandte Chemie: International Edition 50 (6), pp. 1435-1438.

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Other URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.201005910/full


A giant organometallic molecule and a 2D coordination polymer are formed by template-assisted self-assembly between CuCl and the cyclo-P5 complex [Cp*Fe(η5-P5)]. The giant capsular molecule exhibits a skeleton of 110 inorganic core atoms and consists of two half-shells with threefold symmetry. Dipersion forces between two encapsulated [Cp*Fe(η5-P5)] guest complexes and half-shells are responsible for the cohesion of the capsule (see structure and model; Cp*=η5-C5Me5).

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Item type:Article
Date:5 January 2011
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:capsules; host–guest systems; phosphorus; self-assembly; supramolecular chemistry
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:19886
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