Vannada, Jagadeshwar, Niehues, Lennart, König, Burkhard and Mehta, Goverdhan (2013) A total synthesis of the epoxyquinone natural product cytosporin D. Tetrahedron 69, pp. 6034-6040.
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Abstract
A synthesis of epoxyquinone natural product cytosporin D from the readily available DielseAlder adduct of cyclopentadiene and 2-prenyl-p-benzoquinone, has been accomplished. This approach leverages the stereochemical predisposition of the norbornyl-fused systems towards convex face reactivity as an enabler
for the stereoselective construction of the pyran ring.
Export bibliographical data
| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2013 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König | ||||
| Projects: | Indigo | ||||
| Identification Number: |
| ||||
| Keywords: | Epoxyquinone natural products;Diels-Alder reaction; Stereoselective reduction; Wittig olefination; Oxycylization | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 28375 |
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