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Kinetic laws, phase-phase expansions, renormalization group, and INR calibration

Vlad, Marcel O. ; Corlan, Alexandru D. ; Morán, Federico ; Spang, Rainer ; Oefner, Peter J. ; Ross, John


We introduce systematic approaches to chemical kinetics based on the use of phase-phase (log-log) representations of the rate equations. For slow processes, we obtain a corrected form of the mass-action law, where the concentrations are replaced by kinetic activities. For fast reactions, delay expressions are derived. The phase-phase expansion is, in general, applicable to kinetic and transport ...


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