Go to content
UR Home

A Nano-sized Supramolecule Beyond the Fullerene Topology

Dielmann, Fabian, Heindl, Claudia, Hastreiter, F., Peresypkina, E. V., Virovets, A. V., Gschwind, R. M. and Scheer, M. (2014) A Nano-sized Supramolecule Beyond the Fullerene Topology. Angewandte Chemie International Edition, pp. 13605-13608.

[img]
Preview
License: Creative Commons Attribution 3.0
PDF - Published Version
Download (1MB)
Date of publication of this fulltext: 24 Nov 2014 07:11

at publisher (via DOI)


Abstract

The reaction of [CpBnFe(η5-P5)] (1) (CpBn=η5-C5(CH2Ph)5) with CuI selectively yields a novel spherical supramolecule (CH2Cl2)3.4@[(CpBnFeP5)12{CuI}54(MeCN)1.46] (2) showing a linkage of the scaffold atoms which is beyond the Fullerene topology. Its extended CuI framework reveals an outer diameter of 3.7 nm—a size that has not been reached before using five-fold symmetric building blocks. ...

plus


Export bibliographical data



Item type:Article
Date:2014
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1002/anie.201407120DOI
Keywords:copper Cp ligands phosphorus self-assembly supramolecular chemistry
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:30986
Owner only: item control page

Downloads

Downloads per month over past year

  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de

Dissertations: dissertationen@ur.de

Research data: daten@ur.de

Contact persons