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A Nano-sized Supramolecule Beyond the Fullerene Topology

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Dielmann, Fabian ; Heindl, Claudia ; Hastreiter, F. ; Peresypkina, E. V. ; Virovets, A. V. ; Gschwind, R. M. ; Scheer, M.
License: Creative Commons: Attribution 3.0
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Date of publication of this fulltext: 24 Nov 2014 07:11


The reaction of [CpBnFe(η5-P5)] (1) (CpBn=η5-C5(CH2Ph)5) with CuI selectively yields a novel spherical supramolecule (CH2Cl2)3.4@[(CpBnFeP5)12{CuI}54(MeCN)1.46] (2) showing a linkage of the scaffold atoms which is beyond the Fullerene topology. Its extended CuI framework reveals an outer diameter of 3.7 nm—a size that has not been reached before using five-fold symmetric building blocks. ...


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