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A Nano-sized Supramolecule Beyond the Fullerene Topology

URN to cite this document:
urn:nbn:de:bvb:355-epub-309863
DOI to cite this document:
10.5283/epub.30986
Dielmann, Fabian ; Heindl, Claudia ; Hastreiter, F. ; Peresypkina, E. V. ; Virovets, A. V. ; Gschwind, R. M. ; Scheer, M.
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Date of publication of this fulltext: 24 Nov 2014 07:11


Abstract

The reaction of [(CpFe)-Fe-Bn(eta(5)-P-5)] (1) (Cp-Bn = eta(5)-C-5(CH2Ph)(5)) with CuI selectively yields a novel spherical supramolecule (CH2Cl2)3.4@[((CpFeP5)-Fe-Bn)(12){CuI}(54)(MeCN)(1.46)] (2) showing a linkage of the scaffold atoms which is beyond the Fullerene topology. Its extended CuI framework reveals an outer diameter of 3.7 nm-a size that has not been reached before using five-fold ...

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