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A Nano-sized Supramolecule Beyond the Fullerene Topology

Dielmann, Fabian, Heindl, Claudia, Hastreiter, F., Peresypkina, E. V., Virovets, A. V., Gschwind, R. M. and Scheer, M. (2014) A Nano-sized Supramolecule Beyond the Fullerene Topology. Angewandte Chemie International Edition, pp. 13605-13608.

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Date of publication of this fulltext: 24 Nov 2014 07:11

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The reaction of [CpBnFe(η5-P5)] (1) (CpBn=η5-C5(CH2Ph)5) with CuI selectively yields a novel spherical supramolecule (CH2Cl2)3.4@[(CpBnFeP5)12{CuI}54(MeCN)1.46] (2) showing a linkage of the scaffold atoms which is beyond the Fullerene topology. Its extended CuI framework reveals an outer diameter of 3.7 nm—a size that has not been reached before using five-fold symmetric building blocks. ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
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Keywords:copper Cp ligands phosphorus self-assembly supramolecular chemistry
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:30986
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