Heindl, Claudia, Peresypkina, Eugenia V., Virovets, Alexander V., Komarov, Vladislav Yu. and Scheer, Manfred
(2015)
1,2,4-Triphospholyl anions – versatile building blocks for the formation of 1D, 2D and 3D assemblies.
Dalton Transactions 44, pp. 10245-10252.
Date of publication of this fulltext: 12 Feb 2016 11:13at publisher (via DOI)
Abstract
The potential of K[P3C2R2] (R = tBu, Mes) as building blocks in metallo-supramolecular chemistry was investigated and self-assembly processes with Cu(I) halides resulted in the formation of a large variety of unprecedented one-, two- and even three-dimensional aggregates. The 3D networks showed an interesting topological similarity to allotropes of carbon: diamond and the theoretically proposed ...
Abstract
The potential of K[P3C2R2] (R = tBu, Mes) as building blocks in metallo-supramolecular chemistry was investigated and self-assembly processes with Cu(I) halides resulted in the formation of a large variety of unprecedented one-, two- and even three-dimensional aggregates. The 3D networks showed an interesting topological similarity to allotropes of carbon: diamond and the theoretically proposed polybenzene. Furthermore, the negative charge of the phospholyl ligand favoured the generation of cationic CuaXb (a > b, X = Cl, Br, I) assemblies, a challenging area within the well-studied coordination chemistry of CuX units. In addition, the 1D strands were also characterized in solution, revealing the presence of oligomeric units.
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