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1,2,4-Triphospholyl anions – versatile building blocks for the formation of 1D, 2D and 3D assemblies

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Heindl, Claudia ; Peresypkina, Eugenia V. ; Virovets, Alexander V. ; Komarov, Vladislav Yu. ; Scheer, Manfred
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Date of publication of this fulltext: 12 Feb 2016 11:13


The potential of K[P3C2R2] (R = tBu, Mes) as building blocks in metallo-supramolecular chemistry was investigated and self-assembly processes with Cu(I) halides resulted in the formation of a large variety of unprecedented one-, two- and even three-dimensional aggregates. The 3D networks showed an interesting topological similarity to allotropes of carbon: diamond and the theoretically proposed ...


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