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Halogenase-Inspired Oxidative Chlorination Using Flavin
Photocatalysis

Hering, Thea, Mühldorf, Bernd, Wolf, Robert and König, Burkhard (2016) Halogenase-Inspired Oxidative Chlorination Using Flavin
Photocatalysis.
Angewandte Chemie International Edition 55, pp. 5342-5345.

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Abstract

Chemists use chlorine gas or electropositive chlorine reagents, such as NCS, to prepare chlorinated aromatic compounds, which are found in pharmaceuticals, agrochemicals, and polymers and serve as synthetic precursors for metal-catalyzed cross couplings. Nature chlorinates with chloride anions, FAD-dependent halogenases and O2 as the oxidant. We describe now a photocatalytic oxidative ...

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Item type:Article
Date:2016
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf
Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1002/anie.201600783DOI
26991557PubMed ID
Keywords:photocatalysis • enzyme models• flavins • oxidative chlorination
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:33496
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