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Halogenase-Inspired Oxidative Chlorination Using Flavin
Photocatalysis

Hering, Thea ; Mühldorf, Bernd ; Wolf, Robert ; König, Burkhard



Zusammenfassung

Chlorine gas or electropositive chlorine reagents are used to prepare chlorinated aromatic compounds, which are found in pharmaceuticals, agrochemicals, and polymers, and serve as synthetic precursors for metal-catalyzed cross-couplings. Nature chlorinates with chloride anions, FAD-dependent halogenases, and O-2 as the oxidant. A photocatalytic oxidative chlorination is described based on the ...

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