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Benzotriazolate cage complexes of tin(II) and lithium: halide-influenced serendipitous assembly

Bodensteiner, Michael, Scheuermeyer, Sabine, Scheer, Manfred, Zabel, Manfred, Sulway, Scott A. and Layfield, Richard A. (2011) Benzotriazolate cage complexes of tin(II) and lithium: halide-influenced serendipitous assembly. Dalton Transactions 40, pp. 7559-7563.

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Abstract

The one-pot reactions of the tin(II) halides SnX2 (X = F, Cl, Br, I) with lithium hexamethyldisilazide, [Li(hmds)], and benzotriazole, (bta)H, produce contrasting outcomes. Tin(II) fluoride does not react with [Li(hmds)] and (bta)H, the outcome being the formation of insoluble [Li(bta)]∞. Tin(II) chloride and tin(II) bromide react with [Li(hmds)] and (bta)H in toluene to produce the ...

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Item type:Article
Date:2011
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1039/c1dt10400dDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:34140
Owner only: item control page

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