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Spin crossover in phosphorus- and arsenic-bridged cyclopentadienyl-manganese(II) dimers

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DOI to cite this document:
Scheuermayer, S. ; Tuna, F. ; Bodensteiner, Michael ; Scheer, Manfred ; Layfield, Richard A.
License: Allianz- bzw. Nationallizenz
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Date of publication of this fulltext: 02 Aug 2016 06:25


Manganocene reacts with LiE(SiMe3)2 (E = P or As) to give [(η5-Cp)Mn{μ-E(SiMe3)2}]2, where E = P (1) or As (2). The temperature dependence of the magnetic susceptibility in 1 and 2 is due to antiferromagnetic exchange and to spin-crossover (SCO). Compound 2 shows two-step SCO with hysteresis, involving high-spin (S = 5/2) and intermediate-spin S = (3/2) Mn(II).

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