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Spin crossover in phosphorus- and arsenic-bridged cyclopentadienyl-manganese(II) dimers

Scheuermayer, S., Tuna, F., Bodensteiner, Michael, Scheer, Manfred and Layfield, Richard A. (2012) Spin crossover in phosphorus- and arsenic-bridged cyclopentadienyl-manganese(II) dimers. Chemical Communications : ChemComm 48, pp. 8087-8089.

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Manganocene reacts with LiE(SiMe3)2 (E = P or As) to give [(η5-Cp)Mn{μ-E(SiMe3)2}]2, where E = P (1) or As (2). The temperature dependence of the magnetic susceptibility in 1 and 2 is due to antiferromagnetic exchange and to spin-crossover (SCO). Compound 2 shows two-step SCO with hysteresis, involving high-spin (S = 5/2) and intermediate-spin S = (3/2) Mn(II).

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:34196
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