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Stepwise activation of “non-innocent” Cp* substituents – a Cp* based cascade reaction

URN to cite this document:
urn:nbn:de:bvb:355-epub-341976
Stubenhofer, Markus ; Lassandro, Giuliano ; Balazs, Gabor ; Timoshkin, Alexey Y. ; Scheer, Manfred
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Date of publication of this fulltext: 02 Aug 2016 06:23


Abstract

Reactions of Cp* substituted pentelidene complexes with the primary phosphine Cp*PH2 yield novel polycyclic phosphorus/arsenic and carbon containing cage compounds via cascade-like reactions. These reactions include a sequence of nucleophilic addition reactions, intramolecular hydrophosphination (partially hydroarsination) reactions, retro-Diels–Alder reactions with Cp*H elimination and subsequent [2+4]-cycloadditions.


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