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Stepwise activation of “non-innocent” Cp* substituents – a Cp* based cascade reaction

Stubenhofer, Markus, Lassandro, Giuliano, Balazs, Gabor, Timoshkin, Alexey Y. and Scheer, Manfred (2012) Stepwise activation of “non-innocent” Cp* substituents – a Cp* based cascade reaction. Chemical Communications 48, pp. 7262-7264.

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Date of publication of this fulltext: 02 Aug 2016 06:23

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Reactions of Cp* substituted pentelidene complexes with the primary phosphine Cp*PH2 yield novel polycyclic phosphorus/arsenic and carbon containing cage compounds via cascade-like reactions. These reactions include a sequence of nucleophilic addition reactions, intramolecular hydrophosphination (partially hydroarsination) reactions, retro-Diels–Alder reactions with Cp*H elimination and subsequent [2+4]-cycloadditions.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:34197
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