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Visible-Light-Accelerated C−H Sulfinylation of Heteroarenes

Meyer, Andreas Uwe , Wimmer, Alexander and König, Burkhard (2017) Visible-Light-Accelerated C−H Sulfinylation of Heteroarenes. Angewandte Chemie International Edition 56, pp. 409-412.

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Abstract

Heteroaromatic sulfoxides are a frequent structural motif in natural products, drugs, catalysts, and materials. We report a metal-free visible-light-accelerated synthesis of heter-oaromatic sulfoxides from sulfinamides and peroxodisulfate. The reaction proceeds at room temperature with blue-light irradiation and allows the C-H sulfinylation of electron-rich heteroarenes, such as pyrroles and ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1002/anie.201610210DOI
Keywords:PALLADIUM-CATALYZED ARYLATION; TRANSITION-METAL CATALYSIS; ARYL BENZYL SULFOXIDES; SULFENATE ANIONS; ENANTIOENRICHED SULFOXIDES; ENANTIOSELECTIVE SYNTHESIS; NUCLEOPHILIC REACTIVITIES; ASYMMETRIC CATALYSIS; PHOTOREDOX CATALYSIS; DIARYL SULFOXIDES; Friedel-Crafts reaction; metal-free conditions; sulfinylation; sulfoxide; visible light
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
600 Technology > 615 Pharmacy
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:34965
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