Influence of β-diiminato Ligand Design in Transition Metal Mediated E4 (E = P, As) Activation

URN to cite this document:: urn:nbn:de:bvb:355-epub-359069
DOI to cite this document:: 10.5283/epub.35906

Spitzer, Fabian

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Date of publication of this fulltext: 25 Jun 2018 07:15

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Item type:	Thesis of the University of Regensburg (PhD)
Open Access Type:	Primary Publication
Date:	25 June 2018
Referee:	Prof. Dr. Manfred Scheer
Date of exam:	23 June 2017
Institutions:	Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Keywords:	small molecule activation, P4, As4, β-diiminato ligand
Dewey Decimal Classification:	500 Science > 540 Chemistry & allied sciences
Status:	Published
Refereed:	Yes, this version has been refereed
Created at the University of Regensburg:	Yes
Item ID:	35906

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Abstract (English)

This work provides a detailed insight into the reactivity of late transition metal (Fe, Co, Cu) complexes towards white phosphorus (P4) and yellow arsenic (As4). Of particular interest is the application of differently substituted β-diiminato supporting ligands and their influence on the En ligand complex formation (E = P, As).

Translation of the abstract (German)

Diese Arbeit bietet detaillierte Einblicke in die Reaktivität von Komplexen später Übergangsmetalle (Fe, Co, Cu) gegenüber weißem Phosphor (P4) und gelbem Arsen (As4). Von besonderer Bedeutung ist die Anwendung unterschiedlich substituierter β-diiminato Hilfsliganden und deren Einfluss auf die En-Ligandkomplex Ausbildung (E = P, As).

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