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Controlled Antibody Release from Degradable Thermoresponsive
Hydrogels Cross-Linked by Diels−Alder Chemistry

Gregoritza, Manuel ; Messmann, Viktoria ; Abstiens, Kathrin ; Brandl, Ferdinand ; Göpferich, Achim



Abstract

Amine-modified four- and eight-armed poloxamines were prepared and subsequently functionalized with maleimide or fury' groups. Aqueous solutions of these polymers exhibited an immediate gelation at a temperature above 37 C. Concomitantly, Diets Alder reactions gradually cross-linked and cured the gels. Different ratios between four- and eight-armed macromonomers were used to tune hydrogel ...

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