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Oxidative homodimerization of substituted olefins by DDQ visible light photocatalysis

Chuskit, Deachen, Chaudhary, Renu, Venugopalan, Paloth, König, Burkhard and Natarajan, Palani (2018) Oxidative homodimerization of substituted olefins by DDQ visible light photocatalysis. Organic Chemistry Frontiers 5, pp. 3553-3556.

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A visible-light-mediated dehydrogenative homocoupling reaction of readily available mono- and disubstituted olefins to afford symmetrical di- and tetrasubstituted buta-1,3-dienes in the presence of catalytic amounts of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) has been developed. The reaction proceeds for a wide range of substrates giving buta-1,3-dienes in moderate to good yields. We ...


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Item type:Article
Additional Information (public):Advance Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
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Keywords:visible light photocatalysis
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:38079
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