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Single-molecule photoredox catalysis

Haimerl, Josef ; Ghosh, Indrajit ; König, Burkhard ; Vogelsang, Jan ; Lupton, John M.



Abstract

The chemistry of life is founded on light, so is it appropriate to think of light as a chemical substance? Planck's quantization offers a metric analogous to Avogadro's number to relate the number of particles to an effective reaction of single molecules and photons to form a new compound. A rhodamine dye molecule serves as a dehalogenating photocatalyst in a consecutive photoelectron transfer ...

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