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The Cobalt cyclo -P4 Sandwich Complex and Its Role in the Formation of Polyphosphorus Compounds

Dielmann, Fabian, Timoshkin, Alexey , Piesch, Martin, Balázs, Gábor and Scheer, Manfred (2017) The Cobalt cyclo -P4 Sandwich Complex and Its Role in the Formation of Polyphosphorus Compounds. Angewandte Chemie International Edition 56 (6), pp. 1671-1675.

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Other URL: http://doi.org/10.1002/anie.201610967


Abstract

A synthetic approach to the sandwich complex [CpCo((4)-P-4)] (2) containing a cyclo-P-4 ligand as an end-deck was developed. Complex 2 is the missing homologue in the series of first-row cyclo-P-n sandwich complexes, and shows a unique tendency to dimerize in solution to form two isomeric P-8 complexes [(CpCo)(2)(,(4):(2):(1)-P-8)] (3 and 4). Reactivity studies indicate that 2 and 3 react with ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.201610967DOI
Keywords:SYMMETRICAL P-4 CLEAVAGE; ORGANIC HYBRID MATERIALS; FULLERENE TOPOLOGY; SPHERICAL CLUSTER; BUILDING-BLOCKS; METAL-COMPLEXES; LIGANDS; PHOSPHORUS; ACTIVATION; PENTAPHOSPHAFERROCENE; cobalt; coordination modes; cyclo-P-4 complexes; phosphorus; sandwich complexes
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38756
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