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The Cobalt cyclo -P4 Sandwich Complex and Its Role in the Formation of Polyphosphorus Compounds

Dielmann, Fabian ; Timoshkin, Alexey ; Piesch, Martin ; Balázs, Gábor ; Scheer, Manfred


A synthetic approach to the sandwich complex [CpCo((4)-P-4)] (2) containing a cyclo-P-4 ligand as an end-deck was developed. Complex 2 is the missing homologue in the series of first-row cyclo-P-n sandwich complexes, and shows a unique tendency to dimerize in solution to form two isomeric P-8 complexes [(CpCo)(2)(,(4):(2):(1)-P-8)] (3 and 4). Reactivity studies indicate that 2 and 3 react with ...


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