Dielmann, Fabian, Timoshkin, Alexey 
, Piesch, Martin, Balázs, Gábor and Scheer, Manfred
(2017)
The Cobalt cyclo -P4 Sandwich Complex and Its Role in the Formation of Polyphosphorus Compounds.
Angewandte Chemie International Edition 56 (6), pp. 1671-1675.
Full text not available from this repository.
Other URL: http://doi.org/10.1002/anie.201610967
Abstract
A synthetic approach to the sandwich complex [CpCo((4)-P-4)] (2) containing a cyclo-P-4 ligand as an end-deck was developed. Complex 2 is the missing homologue in the series of first-row cyclo-P-n sandwich complexes, and shows a unique tendency to dimerize in solution to form two isomeric P-8 complexes [(CpCo)(2)(,(4):(2):(1)-P-8)] (3 and 4). Reactivity studies indicate that 2 and 3 react with ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2017 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number: |
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| Keywords: | SYMMETRICAL P-4 CLEAVAGE; ORGANIC HYBRID MATERIALS; FULLERENE TOPOLOGY; SPHERICAL CLUSTER; BUILDING-BLOCKS; METAL-COMPLEXES; LIGANDS; PHOSPHORUS; ACTIVATION; PENTAPHOSPHAFERROCENE; cobalt; coordination modes; cyclo-P-4 complexes; phosphorus; sandwich complexes | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 38756 |
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