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Synthesis and structural characterization of Ni(II) complexes with the chiral CpH(PNMent) tripod ligand

Tsuno, Takashi , Sugiyama, Yu, Brunner, Henri, Bodensteiner, Michael and Lee, Kosei (2017) Synthesis and structural characterization of Ni(II) complexes with the chiral CpH(PNMent) tripod ligand. Journal of Coordination Chemistry 70 (20), pp. 3459-3470.

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Other URL: http://doi.org/10.1080/00958972.2017.1390222


Abstract

Treatment of NiCl2 with the tripod ligand (L-Ment, S-C)-1H led to (L-Ment, S-C)-[Cp(PNMent) NiCl] in which the potentially tridentate ligand coordinated to the metal center in a bidentate way via the cyclopentadienyl system and the phosphorus atom. In the presence of NH4PF6 [(L-Ment, S-C)[Cp(PNMent) NiCl] readily underwent Cl/PPh3 exchange to give (L-Ment, S-C)-[Cp(PNMent) NiPPh3] PF6. Reaction ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1080/00958972.2017.1390222DOI
Keywords:LABILE METAL CONFIGURATION; NICKEL NHC COMPLEXES; CRYSTAL-STRUCTURES; CYCLOPENTADIENYL; STABILIZATION; ELECTROCHEMISTRY; POLYMERIZATION; DERIVATIVES; ALKYNYL; RING; Ni(II) complexes; Chiral-at-metal complexes; Tridentate ligand; Crystal structure
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38828
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