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Synthesis and structural characterization of Ni(II) complexes with the chiral CpH(PNMent) tripod ligand

Tsuno, Takashi ; Sugiyama, Yu ; Brunner, Henri ; Bodensteiner, Michael ; Lee, Kosei


Treatment of NiCl2 with the tripod ligand (L-Ment, S-C)-1H led to (L-Ment, S-C)-[Cp(PNMent) NiCl] in which the potentially tridentate ligand coordinated to the metal center in a bidentate way via the cyclopentadienyl system and the phosphorus atom. In the presence of NH4PF6 [(L-Ment, S-C)[Cp(PNMent) NiCl] readily underwent Cl/PPh3 exchange to give (L-Ment, S-C)-[Cp(PNMent) NiPPh3] PF6. Reaction ...


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