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Arsenic-Rich Polyarsenides Stabilized by Cp*Fe Fragments

Schmidt, Monika, Konieczny, David, Peresypkina, Eugenia V., Virovets, Alexander V. , Balázs, Gabor, Bodensteiner, Michael, Riedlberger, Felix, Krauss, Hannes and Scheer, Manfred (2017) Arsenic-Rich Polyarsenides Stabilized by Cp*Fe Fragments. Angewandte Chemie International Edition 56 (25), pp. 7307-7311.

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Other URL: http://doi.org/10.1002/anie.201702903


Abstract

The redox chemistry of [Cp*Fe(eta(5)-As-5)] (1, Cp* = eta(5)-C5Me5) has been investigated by cyclic voltammetry, revealing a redox behavior similar to that of its lighter congener [Cp*Fe(eta(5)-P-5)]. However, the subsequent chemical reduction of 1 by KH led to the formation of a mixture of novel As-n scaffolds with n up to 18 that are stabilized only by [Cp*Fe] fragments. These include the ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.201702903DOI
Keywords:CRYSTAL-STRUCTURE; ELECTRON-DIFFRACTION; COMPLEXES; CHEMISTRY; PENTAPHOSPHAFERROCENE; FERROCENE; LIGANDS; ANIONS; DIMERIZATION; FULLERENE; arsenic; DFT calculations; iron; polyarsenides; reduction
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38893
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