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Arsenic-Rich Polyarsenides Stabilized by Cp*Fe Fragments

Schmidt, Monika ; Konieczny, David ; Peresypkina, Eugenia V. ; Virovets, Alexander V. ; Balázs, Gabor ; Bodensteiner, Michael ; Riedlberger, Felix ; Krauss, Hannes ; Scheer, Manfred


The redox chemistry of [Cp*Fe(eta(5)-As-5)] (1, Cp* = eta(5)-C5Me5) has been investigated by cyclic voltammetry, revealing a redox behavior similar to that of its lighter congener [Cp*Fe(eta(5)-P-5)]. However, the subsequent chemical reduction of 1 by KH led to the formation of a mixture of novel As-n scaffolds with n up to 18 that are stabilized only by [Cp*Fe] fragments. These include the ...


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