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Cationic Chains of Parent Arsanylboranes and Substituted Phosphanylboranes

Marquardt, Christian, Balázs, Gábor, Baumann, Josef, Virovets, Alexander V. and Scheer, Manfred (2017) Cationic Chains of Parent Arsanylboranes and Substituted Phosphanylboranes. Chemistry - A European Journal 23 (47), pp. 11423-11429.

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Other URL: http://doi.org/10.1002/chem.201702384


The substituted monomeric phosphanylboranes Ph2P-BH2 center dot NMe3 (1) and tBuHP-BH2 center dot NMe3 (2) have been used for the synthesis of cationic chain compounds built up by R2P-BH2 units. With a simple synthesis route, the highly stable cations [Me3N center dot H2B-PR1R2-BH2 center dot NMe3](+) (1a, 2a) and [Me3N center dot H2B-PR1R2-BH2-PR1R2 center dot BH2 center dot NMe3]+(1b, 2b) (R 1 ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:CONVENIENT ROUTE; PHOSPHORUS; CHEMISTRY; DERIVATIVES; COMPLEXES; DICATIONS; BORANE; SALTS; PHOSPHANES; BONDS; arsenic; boron; cationic chains; phosphorus; pnictogenylboranes
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39257
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