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Cationic Chains of Parent Arsanylboranes and Substituted Phosphanylboranes

Marquardt, Christian ; Balázs, Gábor ; Baumann, Josef ; Virovets, Alexander V. ; Scheer, Manfred


The substituted monomeric phosphanylboranes Ph2P-BH2 center dot NMe3 (1) and tBuHP-BH2 center dot NMe3 (2) have been used for the synthesis of cationic chain compounds built up by R2P-BH2 units. With a simple synthesis route, the highly stable cations [Me3N center dot H2B-PR1R2-BH2 center dot NMe3](+) (1a, 2a) and [Me3N center dot H2B-PR1R2-BH2-PR1R2 center dot BH2 center dot NMe3]+(1b, 2b) (R 1 ...


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