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Isomerization, Ring Expansion, and Ring Contraction of 1,3-Diphosphete Complexes

Rummel, Eva-Maria ; Balázs, Gábor ; Heinl, Veronika ; Scheer, Manfred


Reactions between the 1,3-diphosphete complex [Cp''' Co(h 4-P(2)C(2)tBu(2))] (1) and Ag[Al{OC(CF3)(3)}(4)] (Ag[pftb]) were carried out under different conditions. In CH2Cl2, the unprecedented 1,2-diphosphete isomerization product [Ag-2{Cp'''Co(mu,eta(4):eta(1):eta(1)-1,2-P(2)C(2)tBu(2))}(2){Cp'''Co(mu,eta(4):eta(1)-1,2-P(2)C(2)tBu(2))}(2)]center dot 2[pftb] (2) could be isolated. In diffusion ...


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