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Isomerization, Ring Expansion, and Ring Contraction of 1,3-Diphosphete Complexes

Rummel, Eva-Maria, Balázs, Gábor, Heinl, Veronika and Scheer, Manfred (2017) Isomerization, Ring Expansion, and Ring Contraction of 1,3-Diphosphete Complexes. Angewandte Chemie International Edition 56 (32), pp. 9592-9596.

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Other URL: http://doi.org/10.1002/anie.201703633


Abstract

Reactions between the 1,3-diphosphete complex [Cp''' Co(h 4-P(2)C(2)tBu(2))] (1) and Ag[Al{OC(CF3)(3)}(4)] (Ag[pftb]) were carried out under different conditions. In CH2Cl2, the unprecedented 1,2-diphosphete isomerization product [Ag-2{Cp'''Co(mu,eta(4):eta(1):eta(1)-1,2-P(2)C(2)tBu(2))}(2){Cp'''Co(mu,eta(4):eta(1)-1,2-P(2)C(2)tBu(2))}(2)]center dot 2[pftb] (2) could be isolated. In diffusion ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.201703633DOI
Keywords:PHOSPHA-ORGANOMETALLIC COMPOUNDS; CARBON MULTIPLE BONDS; METAL-VAPOR SYNTHESIS; BUILDING-BLOCKS; COORDINATION BEHAVIOR; SANDWICH ANIONS; STRUCTURAL-CHARACTERIZATION; PHOSPHIRENYL CATION; MOLECULAR-STRUCTURE; PI-COMPLEXES; cobalt; diphosphete complexes; phosphaalkynes; silver; weakly coordinating anions
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39295
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