Rummel, Eva-Maria, Balázs, Gábor, Heinl, Veronika and Scheer, Manfred (2017) Isomerization, Ring Expansion, and Ring Contraction of 1,3-Diphosphete Complexes. Angewandte Chemie International Edition 56 (32), pp. 9592-9596.
Full text not available from this repository.
Other URL: http://doi.org/10.1002/anie.201703633
Abstract
Reactions between the 1,3-diphosphete complex [Cp''' Co(h 4-P(2)C(2)tBu(2))] (1) and Ag[Al{OC(CF3)(3)}(4)] (Ag[pftb]) were carried out under different conditions. In CH2Cl2, the unprecedented 1,2-diphosphete isomerization product [Ag-2{Cp'''Co(mu,eta(4):eta(1):eta(1)-1,2-P(2)C(2)tBu(2))}(2){Cp'''Co(mu,eta(4):eta(1)-1,2-P(2)C(2)tBu(2))}(2)]center dot 2[pftb] (2) could be isolated. In diffusion ...
Export bibliographical data
| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2017 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number: |
| ||||
| Keywords: | PHOSPHA-ORGANOMETALLIC COMPOUNDS; CARBON MULTIPLE BONDS; METAL-VAPOR SYNTHESIS; BUILDING-BLOCKS; COORDINATION BEHAVIOR; SANDWICH ANIONS; STRUCTURAL-CHARACTERIZATION; PHOSPHIRENYL CATION; MOLECULAR-STRUCTURE; PI-COMPLEXES; cobalt; diphosphete complexes; phosphaalkynes; silver; weakly coordinating anions | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 39295 |
Owner only: item control page
Altmetric