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Coordination Behavior of [Cp′′ 2 Zr(η 1:1 ‐P 4 )] towards Different Lewis Acids

Seitz, Andreas E. ; Vogel, Ulf ; Eberl, Miriam ; Eckhardt, Maria ; Balázs, Gábor ; Peresypkina, Eugenia V. ; Bodensteiner, Michael ; Zabel, Manfred ; Scheer, Manfred


A detailed method for the preparation of [Cp '' Zr-2(eta(1:1)-P-4)](1) is presented. The coordination behavior of 1 towards Lewis acidic transition metal complexes of tungsten, manganese, and iron, respectively, and main group compounds (AlMe3, AlEt3) was investigated in detail by computational and experimental studies. In doing so, a series of unprecedented complexes with different coordi- ...


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