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Preorganized AgI Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic-Organic Hybrid Polymers

Moussa, Mehdi Elsayed, Seidl, Michael, Balázs, Gábor, Zabel, Manfred, Virovets, Alexander V. , Attenberger, Bianca, Schreiner, Andrea and Scheer, Manfred (2017) Preorganized AgI Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic-Organic Hybrid Polymers. Chemistry - A European Journal 23 (64), pp. 16199-16203.

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Other URL: http://doi.org/10.1002/chem.201704582


Abstract

An Ag-I dimer capped with labile organometallic diphosphorus ligands [Cp2Mo2(CO)(4)(eta(2)-P-2)] (Cp = C5H5) acts as a highly pre-organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic-organic hybrid coordination polymers upon reaction with ditopic pyridine-based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations.


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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/chem.201704582DOI
Keywords:STACKED SUPRAMOLECULAR ASSEMBLIES; COORDINATION POLYMERS; BUILDING-BLOCKS; ANTICANCER ACTIVITY; DONOR LIGANDS; COMPLEXES; FRAMEWORKS; DESIGN; METALLACYCLES; GOLD(I); controlled synthesis; diphosphorus complex; hybrid coordination polymers; organometallic node; preorganized precursor
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39565
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