Moussa, Mehdi Elsayed, Seidl, Michael, Balázs, Gábor, Zabel, Manfred, Virovets, Alexander V. 
, Attenberger, Bianca, Schreiner, Andrea and Scheer, Manfred
(2017)
Preorganized AgI Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic-Organic Hybrid Polymers.
Chemistry - A European Journal 23 (64), pp. 16199-16203.
Full text not available from this repository.
Other URL: http://doi.org/10.1002/chem.201704582
Abstract
An Ag-I dimer capped with labile organometallic diphosphorus ligands [Cp2Mo2(CO)(4)(eta(2)-P-2)] (Cp = C5H5) acts as a highly pre-organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic-organic hybrid coordination polymers upon reaction with ditopic pyridine-based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations.
Export bibliographical data
| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2017 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number: |
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| Keywords: | STACKED SUPRAMOLECULAR ASSEMBLIES; COORDINATION POLYMERS; BUILDING-BLOCKS; ANTICANCER ACTIVITY; DONOR LIGANDS; COMPLEXES; FRAMEWORKS; DESIGN; METALLACYCLES; GOLD(I); controlled synthesis; diphosphorus complex; hybrid coordination polymers; organometallic node; preorganized precursor | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 39565 |
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