Moussa, Mehdi Elsayed, Seidl, Michael, Balázs, Gábor, Zabel, Manfred, Virovets, Alexander V. , Attenberger, Bianca, Schreiner, Andrea and Scheer, Manfred
(2017)
Preorganized AgI Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic-Organic Hybrid Polymers.
Chemistry - A European Journal 23 (64), pp. 16199-16203.
Full text not available from this repository.
Other URL: http://doi.org/10.1002/chem.201704582
Abstract
An Ag-I dimer capped with labile organometallic diphosphorus ligands [Cp2Mo2(CO)(4)(eta(2)-P-2)] (Cp = C5H5) acts as a highly pre-organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic-organic hybrid coordination polymers upon reaction with ditopic pyridine-based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations.
Export bibliographical data
Item type: | Article | ||||
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Date: | 2017 | ||||
Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
Identification Number: |
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Keywords: | STACKED SUPRAMOLECULAR ASSEMBLIES; COORDINATION POLYMERS; BUILDING-BLOCKS; ANTICANCER ACTIVITY; DONOR LIGANDS; COMPLEXES; FRAMEWORKS; DESIGN; METALLACYCLES; GOLD(I); controlled synthesis; diphosphorus complex; hybrid coordination polymers; organometallic node; preorganized precursor | ||||
Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
Status: | Published | ||||
Refereed: | Yes, this version has been refereed | ||||
Created at the University of Regensburg: | Yes | ||||
Item ID: | 39565 |