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Implementing functionality in molecular self-assembled monolayers

Kocić, Nemanja ; Blank, Dominik ; Abufager, Paula ; Lorente, Nicolas ; Decurtins, Silvio ; Liu, Shi-Xia ; Repp, Jascha



Abstract

The planar heterocyclic molecules 1,6,7,12-tetraazaperylene on an Ag(111) metal substrate show different charging characteristics depending on their local environment: next to vacancies in self-assembled islands, molecules can be charged by local electric fields, whereas their charge state is fixed otherwise. This enables the activation of selected molecules inside islands by vacancy creation ...

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