The Potential of the Diphosphorus Complex [Cp2W2(CO)4(ƞ2-P2)] as an Organometallic Connecter in Supramolecular Chemistry

URN to cite this document:: urn:nbn:de:bvb:355-epub-417281
DOI to cite this document:: 10.5283/epub.41728

Elsayed-Mousa, Mehdi ; Shelyganov, Pavel ; Wegley, Brian Keith ; Seidl, Michael ; Scheer, Manfred

Preview

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
PDF - Published Version
(2MB)

Date of publication of this fulltext: 02 Mar 2020 09:38

Alternative links to fulltext:DOI Publisher

This publication is part of the DEAL contract with Wiley.

Details

Preview

Indexed in

Export bibliographical data

Abstract

For the first time, the tetrahedral diphosphorus complex [Cp2W2(CO)(4)(mu,eta(2):eta(2)-P-2)] (Cp = C5H5) (3) is used as a connecter in supramolecular chemistry. The treatment of 3 with Cu-I halides leads to the formation of the new one-dimensional (1D) linear polymers [Cu(mu-X){Cp2W2(CO)(4)(mu,eta(2):eta(2):eta(1):eta(1)-P-2)}](n) {X = Cl (4), Br (5), I (6)}. The coordination polymers (CPs) 4-6 ...