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The Potential of the Diphosphorus Complex [Cp2W2(CO)4(ƞ2-P2)] as an Organometallic Connecter in Supramolecular Chemistry

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Elsayed-Mousa, Mehdi ; Shelyganov, Pavel ; Wegley, Brian Keith ; Seidl, Michael ; Scheer, Manfred
Date of publication of this fulltext: 02 Mar 2020 09:38

This publication is part of the DEAL contract with Wiley.


For the first time, the tetrahedral diphosphorus complex [Cp2W2(CO)(4)(mu,eta(2):eta(2)-P-2)] (Cp = C5H5) (3) is used as a connecter in supramolecular chemistry. The treatment of 3 with Cu-I halides leads to the formation of the new one-dimensional (1D) linear polymers [Cu(mu-X){Cp2W2(CO)(4)(mu,eta(2):eta(2):eta(1):eta(1)-P-2)}](n) {X = Cl (4), Br (5), I (6)}. The coordination polymers (CPs) 4-6 ...


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