Shugurova, N. V. ; Davydova, E. I. ; Sevast’yanova, T. N. ; Misharev, A. D. ; Bodensteiner, M. ; Scheer, M. 
Alternative Links zum Volltext:DOIVerlag
| Dokumentenart: | Artikel |
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| Titel eines Journals oder einer Zeitschrift: | Russian Journal of General Chemistry |
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| Verlag: | MAIK NAUKA/INTERPERIODICA/SPRINGER |
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| Ort der Veröffentlichung: | NEW YORK |
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| Band: | 86 |
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| Nummer des Zeitschriftenheftes oder des Kapitels: | 1 |
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| Seitenbereich: | S. 9-17 |
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| Datum: | 2016 |
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| Institutionen: | Chemie und Pharmazie > Institut für Anorganische Chemie > Lehrstuhl Prof. Dr. Manfred Scheer |
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| Identifikationsnummer: | | Wert | Typ |
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| 10.1134/S1070363216010035 | DOI |
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| Stichwörter / Keywords: | DONOR-ACCEPTOR BOND; NEUTRAL LEWIS-BASES; TITANIUM TETRACHLORIDE; ADDITION-COMPOUNDS; COMPLEXES; ADDUCTS; COORDINATION; EXCHANGE; CHLORIDE; DENSITY; titanium tetrachloride; diethyl ether; donor-acceptor complexes; ethoxytrichlorotitanium; titanium dioxide |
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| Dewey-Dezimal-Klassifikation: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
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| Status: | Veröffentlicht |
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| Begutachtet: | Ja, diese Version wurde begutachtet |
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| An der Universität Regensburg entstanden: | Ja |
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| Dokumenten-ID: | 41761 |
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Zusammenfassung
The reaction of titanium tetrachloride with diethyl ether at various ratios of components and temperatures was studied by the NMR and mass spectrometry methods. The TiCl4 center dot 2Et(2)O complex does not pass in the gas phase. Formation of ethoxytrichlorotitanium among reaction products was established by the X-ray structure analysis. The model of conversion from initial components to titanium ...
Zusammenfassung
The reaction of titanium tetrachloride with diethyl ether at various ratios of components and temperatures was studied by the NMR and mass spectrometry methods. The TiCl4 center dot 2Et(2)O complex does not pass in the gas phase. Formation of ethoxytrichlorotitanium among reaction products was established by the X-ray structure analysis. The model of conversion from initial components to titanium dioxide was suggested on the basis of the obtained experimental data and quantum-chemical calculations (B3LYP/def2-SVP level of theory).
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