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Self-assembled fibrillar networks of a multifaceted chiral squaramide: supramolecular multistimuli-responsive alcogels

Schiller, Jana ; Alegre-Requena, Juan V. ; Marqués-López, Eugenia ; Herrera, Raquel P. ; Casanovas, Jordi ; Alemán, Carlos ; Díaz Díaz, David



Abstract

Chiral N, N'-disubstituted squaramide 1 has been found to undergo self-assembly in a variety of alcoholic solvents at low concentrations leading to the formation of novel nanostructured supramolecular alcogels. The gels responded to thermal, mechanical, optical and chemical stimuli. Solubility studies, gelation ability tests and computer modeling of a series of structurally related squaramides ...

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