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Supramolecular aggregation of Ni(salen) with (C6F5)2Hg and [o-C6F4Hg]3

Tsunoda, Mitsukimi ; Fleischmann, Martin ; Jones, J. Stuart ; Bhuvanesh, Nattamai ; Scheer, Manfred ; Gabbaï, François P.


As part of our ongoing interest in the supramolecular chemistry of fluorinated organomercurials, we have investigated the interaction of bis(pentafluorophenyl)mercury ((C6F5)(2)Hg), and trimeric (perfluoro-o-phenylene)mercury ([o-C6F4Hg](3)), with nickel(II) N,N'-bis(salicylidene)ethylenediamine) (Ni(salen)). While solution studies monitored by UV-VIS spectroscopy suggest that Ni(salen) interacts ...


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