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Self-Assembly of Reactive Linear Cu3 Building Blocks for Supramolecular Coordination Chemistry and Their Reactivity toward En Ligand Complexes

Fleischmann, Martin ; Dütsch, Luis ; Elsayed Moussa, Mehdi ; Balázs, Gábor ; Kremer, Werner ; Lescop, Christophe ; Scheer, Manfred



Abstract

This study describes the selective synthesis of linear, trinuclear, halide-bridged Cu-I complexes [Cu-3(mu-X)(2)(mu-dpmp)(2)(MeCN)(2)](+) (1a: X = Cl; 1b: X = Br; 1c: X = I) stabilized by the tridentate dpmp ligand obtained by self -assembly reactions in THF/MeCN. Upon drying, the MeCN ligands can be removed and the complexes are transformed to the reactive parent trinuclear ...

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