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Influence of the nacnac Ligand in Iron(I)-Mediated P4 Transformations

Spitzer, Fabian ; Graßl, Christian ; Balázs, Gábor ; Zolnhofer, Eva M. ; Meyer, Karsten ; Scheer, Manfred


A study of P-4 transformations at low-valent iron is presented using -diketiminato (L) Fe-I complexes [LFe(tol)] (tol=toluene; L=L-1 (1a), L-2 (1b), L-3 (1c)) with different combinations of aromatic and backbone substituents at the ligand. The products [(LFe)(4)((4)-(2):(2):(2):(2)-P-8)] (L=L-1 (2a), L-2 (2b)) containing a P-8 core were obtained by the reaction of 1a,b with P-4 in toluene at room ...


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