Go to content
UR Home

Homoleptic Phosphaalkyne Complexes of Silver(I)

Rummel, Eva-Maria ; Mastrorilli, Piero ; Todisco, Stefano ; Latronico, Mario ; Balázs, Gábor ; Virovets, Alexander V. ; Scheer, Manfred



Abstract

By employing silver salts with a weakly coordinating anion Ag[A] ([A]=[FAl{OC12F15}(3)], [Al{OC(CF3)(3)}(4)]), two phosphaalkynes could be coordinated side-on to a bare silver-(I) center to form the unprecedented homoleptic complexes [Ag(eta(2)-P equivalent to CtBu)(2)][FAl{OC12F15}(3)] (1) and [Ag(eta(2)-P equivalent to CtBu)(2)]-[Al{OC(CF3)(3)}(4)] (2). DFT calculations show that the ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de

Dissertations: dissertationen@ur.de

Research data: daten@ur.de

Contact persons