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Reactivity of Polyphosphorus Complexes towards Nucleophiles

URN to cite this document:
urn:nbn:de:bvb:355-epub-438360
DOI to cite this document:
10.5283/epub.43836
Riedlberger, Felix
Date of publication of this fulltext: 27 Sep 2021 06:56


Abstract (English)

The reactivity of different complexes containing polyphosphorus ligands towards nucleophiles was investigated. Different nucleophiles and different reactivity was observed. All new molecules were charcterized by NMR spectroscopy and X-ray investigations. Neutral nucelophiles react with Cp*FeP5 in an equilibrium reactions. Different NMR spectroscopy experiments were needed to explain the dynamic ...

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Translation of the abstract (German)

Die Reaktivität verschiedener Komplexe, die Polyphosphorliganden enthalten, gegenüber Nucleophilen wurde untersucht. Unterschiedliche Nucleophile und unterschiedliche Reaktivität wurden beobachtet. Alle neuen Moleküle wurden durch NMR-Spektroskopie und Röntgenuntersuchungen charakterisiert. Neutrale Nucelophile reagieren mit Cp*FeP5 in Gleichgewichtsreaktionen. Verschiedene ...

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