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Air tightness of hBN encapsulation and its impact on Raman spectroscopy of van der Waals materials
Holler, Johannes, Bauriedl, Lorenz, Korn, Tobias
, Seitz, Andrea, Özyigit, Furkan, Eichinger, Michaela, Schüller, Christian, Watanabe, Kenji, Taniguchi, Takashi, Strunk, Christoph
und Paradiso, Nicola
(2019)
Air tightness of hBN encapsulation and its impact on Raman spectroscopy of van der Waals materials.
2D Materials 7 (1), 015012.
Veröffentlichungsdatum dieses Volltextes: 16 Mrz 2021 14:55
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.45223
Dies ist die aktuelle Version dieses Eintrags.
Zusammenfassung
Raman spectroscopy is a precious tool for the characterization of van der Waals materials, e.g. for the determination of the layer number in thin exfoliated flakes. For sensitive materials, however, this method can be dramatically invasive. In particular, the light intensity required to obtain a significant Raman signal is sufficient to immediately photo-oxidize few-layer thick metallic van der ...
Raman spectroscopy is a precious tool for the characterization of van der Waals materials, e.g. for the determination of the layer number in thin exfoliated flakes. For sensitive materials, however, this method can be dramatically invasive. In particular, the light intensity required to obtain a significant Raman signal is sufficient to immediately photo-oxidize few-layer thick metallic van der Waals materials. In this work we investigated the impact of the environment on Raman characterization of thin NbSe2 crystals. We show that in ambient conditions the flake is locally oxidized even for very low illumination intensity. Based on this extreme sensitivity to the presence of light and oxygen, we could study the air-tightness of the hBN encapsulation method, the most common passivation method for a wide range of 2D material-based devices. We find that only fully encapsulated devices are reliably air-tight. On the contrary, a simple hBN cover from the top does not prevent a slow diffusion of oxygen between the SiO2 surface and the flake itself.
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| Dokumentenart | Artikel |
| Titel eines Journals oder einer Zeitschrift | 2D Materials |
| Verlag: | IOP |
|---|---|
| Band: | 7 |
| Nummer des Zeitschriftenheftes oder des Kapitels: | 1 |
| Seitenbereich: | 015012 |
| Datum | 8 November 2019 |
| Institutionen | Physik > Institut für Experimentelle und Angewandte Physik > Lehrstuhl Professor Weiss > Arbeitsgruppe Christoph Strunk |
| Stichwörter / Keywords | Raman spectroscopy, sensitive 2D materials, photo-oxidation, hBN encapsulation, niobium diselenide |
| Dewey-Dezimal-Klassifikation | 500 Naturwissenschaften und Mathematik > 530 Physik |
| Status | Veröffentlicht |
| Begutachtet | Ja, diese Version wurde begutachtet |
| An der Universität Regensburg entstanden | Ja |
| URN der UB Regensburg | urn:nbn:de:bvb:355-epub-452232 |
| Dokumenten-ID | 45223 |
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