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Ring Contraction by NHC‐Induced Pnictogen Abstraction

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Piesch, Martin ; Reichl, Stephan ; Seidl, Michael ; Balázs, Gábor ; Scheer, Manfred
Date of publication of this fulltext: 31 Mar 2021 16:49

This publication is part of the DEAL contract with Wiley.


The reaction of [Cp ''' Co(eta(4)-P-4)] (1) (Cp '''=1,2,4-tBu(3)C(5)H(2)) with (NHC)-N-Me ((NHC)-N-Me=1,3,4,5-tetramethylimidazol-2-ylidene) leads through NHC-induced phosphorus cation abstraction to the ring contraction product [((NHC)-N-Me)(2)P][Cp ''' Co(eta(3)-P-3)] (2), which represents the first example of an anionic CoP3 complex. Such NHC-induced ring contraction reactions are also ...


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