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Synthesis and Multiple Subsequent Reactivity of Anionic cyclo ‐E 3 Ligand Complexes (E=P, As).
Synthese und mehrfache Folgereaktivität von anionischen cyclo -E3-Ligandkomplexen (E=P, As)

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Piesch, Martin ; Reichl, Stephan ; Seidl, Michael ; Balázs, Gábor ; Scheer, Manfred
Date of publication of this fulltext: 08 Jun 2021 05:23


A synthetic pathway for the synthesis of novel anionic sandwich complexes with a cyclo-E3 (E=P, As) ligand as an end deck was developed giving [Cp′′′Co(η3-E3)]− (Cp′′′=1,2,4-tri-tert-butylcyclopentadienyl, E=P ([5]), As ([6])) in good yields suitable for further reactivity studies. In the reaction with the chlorophosphanes R2PCl (R=Ph, Cy, tBu), neutral complexes with a disubstituted cyclo-E3P ...


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