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E 4 Transfer (E=P, As) to Ni Complexes

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Heinl, Veronika ; Schmidt, Monika ; Eckhardt, Maria ; Eberl, Miriam Denise ; Seitz, Andreas E. ; Balázs, Gábor ; Seidl, Michael ; Scheer, Manfred
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Date of publication of this fulltext: 08 Jun 2021 05:31

This publication is part of the DEAL contract with Wiley.


The use of [Cp '' Zr-2(eta(1:1)-E-4)] (E=P (1 a), As (1 b), Cp ''=1,3-di-tert-butyl-cyclopentadienyl) as phosphorus or arsenic source, respectively, gives access to novel stable polypnictogen transition metal complexes at ambient temperatures. The reaction of 1 a/1 b with [Cp(R)NiBr](2) (Cp(R)=Cp-Bn (1,2,3,4,5-pentabenzyl-cyclopentadienyl), Cp ''' (1,2,4-tri-tert-butyl-cyclopentadienyl)) was ...


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