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E 4 Transfer (E=P, As) to Ni Complexes

URN to cite this document:
urn:nbn:de:bvb:355-epub-459367
DOI to cite this document:
10.5283/epub.45936
Heinl, Veronika ; Schmidt, Monika ; Eckhardt, Maria ; Eberl, Miriam Denise ; Seitz, Andreas E. ; Balázs, Gábor ; Seidl, Michael ; Scheer, Manfred
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Date of publication of this fulltext: 08 Jun 2021 05:31


Abstract

The use of [Cp′′2Zr(η1:1-E4)] (E=P (1 a), As (1 b), Cp′′=1,3-di-tert-butyl-cyclopentadienyl) as phosphorus or arsenic source, respectively, gives access to novel stable polypnictogen transition metal complexes at ambient temperatures. The reaction of 1 a/1 b with [CpRNiBr]2 (CpR=CpBn (1,2,3,4,5-pentabenzyl-cyclopentadienyl), Cp′′′ (1,2,4-tri-tert-butyl-cyclopentadienyl)) was studied, to yield ...

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