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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-462945
- DOI to cite this document:
- 10.5283/epub.46294
Abstract
A simultaneously protonated and functionalized silicide cluster [NHCDippCu(η4-Si9)H]2− was detected and characterized in liquid ammonia by NMR spectroscopy. Key NMR results were corroborated by theoretical calculations. 1H-NMR line-widths at variable temperatures revealed that proton hopping in the metalated complex [NHCDippCu(η4-Si9)H]2− is less pronounced than in the non-complexed silicide ...

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