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Gold(I) Complexes Containing Phosphanyl- and Arsanylborane Ligands

Braese, Jens ; Schinabeck, Alexander ; Bodensteiner, Michael ; Yersin, Hartmut ; Timoshkin, Alexey Y. ; Scheer, Manfred


The structural and photophysical properties of a series of new Au-I compounds have been studied. The reactions of AuCl(tht) with the phosphanyl- and arsanylboranes RREBH2NMe3 (E=P, As; R=H, Ph; R=H, Ph, tBu) afford the complexes [AuCl(RREBH2NMe3)]. In the solid state, [AuCl(H2PBH2NMe3)](2) (2a) is a dimer showing unsupported intermolecular aurophilic interactions with short AuAu distances. In ...


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