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Unexpected differences in the reactivity between the phosphorus and arsenic derivatives [(CpBIGFe)2(μ,η4:4-E4)] (E = P and As)

Heinl, S. ; Timoshkin, A. Y. ; Müller, J. ; Scheer, M.


Different reaction pathways were determined between thermolysis and photolysis reactions of the butterfly complex [{(CpFe)-Fe-BIG(CO)(2)}(2)(,(1:1)-As-4)] (1b). The thermolysis leads to novel arsenic-rich compounds [((CpFe)-Fe-BIG)(2)(,(4:4)-As-4)] (2b), [((CpFe)-Fe-BIG)(3)((3),(4:4:4)-As-6)] (4) and [(CpFe)-Fe-BIG((5)-As-5)] (5), whereas the photolysis of [{(CpFe)-Fe-BIG(CO)(2)}(2)(,(1:1)-E-4)] ...


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