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Soluble tetraarylporphyrin-platinum conjugates as cytotoxic and phototoxic antitumor agents

Lottner, Christian ; Bart, Karl-Christian ; Bernhardt, Günther ; Brunner, Henri


A series of asymmetric tetraarylporphyrins was synthesized from pyrrole, para-substituted oligo- or poly(ethylene glycol) monomethyl ether benzaldehyde and from 4-hydroxybenzaldehyde etherified with diethyl bromomalonate according to the Lindsey method. After hydrolysis of the tetraarylporphyrin esters, the resulting carboxylic acid groups were used to bind platinum fragments. In comparison to ...


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