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Thermal Decomposition of Donor-Stabilized Phosphinoborane PH2 BH2 NMe3 : A Tensimetry Study

Butlak, Alina V. ; Kazakov, Igor V. ; Stauber, Andreas ; Hegen, Oliver ; Scheer, Manfred ; Pomogaeva, Anna V. ; Timoshkin, Alexey Y.


The thermal decomposition of PH2BH2 center dot NMe3 (1) in closed system was studied by static tensimetry with membrane null-manometer. Compound 1 is unstable already at room temperature and partially decomposes with the release of gaseous trimethylamine and nonvolatile polymeric material. Storage of 1 at 311 K for 53 days results in evolution of small amounts of hydrogen and phosphine. At ...


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