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Expanding the limits of amide–triazole isosteric substitution in bisamide-based physical gels

Tautz, Markus ; Torras, Juan ; Grijalvo, Santiago ; Eritja, Ramón ; Saldías, César ; Alemán, Carlos ; Díaz, David Díaz



Abstract

Gelation of organic solvents using N,N '-((1S,2S)-cyclohexane-1,2-diyl)didodecanamide (C-12-Cyc) is driven by its self-assembly via antiparallel hydrogen bonds and van der Waals intermolecular interactions. In this work we carried out a dual isosteric substitution of the two amide groups with 1,2,3-triazole rings affording the corresponding isosteric gelator (click-C-12-Cyc). A detailed ...

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