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Bidentate Phosphanyl‐ and Arsanylboranes

Hegen, Oliver ; Braese, Jens ; Timoshkin, Alexey Y. ; Scheer, Manfred


A new class of neutral bidentate ligands with pnictogenyl-functional sites has been obtained. The reaction of tmeda center dot (BH2I)(2) (1, tmeda=tetramethylethylendiamine) with different phosphanides yields the corresponding bidentate phosphanylboranes tmeda center dot (BH2PH2)(2) (2a), tmeda center dot (BH2PPh2)(2) (2b), and tmeda center dot (BH(2)tBuPH)(2) (2c). This reaction strategy could ...


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