A Structural Diversity of Molecular Alkaline‐Earth‐Metal Polyphosphides: From Supramolecular Wheel to Zintl Ion

URN to cite this document:: urn:nbn:de:bvb:355-epub-493999
DOI to cite this document:: 10.5283/epub.49399

Yadav, Ravi

; Weber, Martin

; Singh, A. K. ; Münzfeld, L. ; Gramüller, Johannes ; Gschwind, Ruth M.

; Scheer, Manfred

; Roesky, Peter W.

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Date of publication of this fulltext: 13 Oct 2021 11:31

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Abstract

A series of molecular group 2 polyphosphides has been synthesized by using air-stable [Cp*Fe(eta(5)-P-5)] (Cp*=C5Me5) or white phosphorus as polyphosphorus precursors. Different types of group 2 reagents such as organo-magnesium, mono-valent magnesium, and molecular calcium hydride complexes have been investigated to activate these polyphosphorus sources. The organo-magnesium complex ...