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A Structural Diversity of Molecular Alkaline‐Earth‐Metal Polyphosphides: From Supramolecular Wheel to Zintl Ion

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Yadav, Ravi ; Weber, Martin ; Singh, A. K. ; Münzfeld, L. ; Gramüller, Johannes ; Gschwind, Ruth M. ; Scheer, Manfred ; Roesky, Peter W.
License: Creative Commons Attribution Non-commercial 4.0
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Date of publication of this fulltext: 13 Oct 2021 11:31


A series of molecular group 2 polyphosphides has been synthesized by using air-stable [Cp*Fe(eta(5)-P-5)] (Cp*=C5Me5) or white phosphorus as polyphosphorus precursors. Different types of group 2 reagents such as organo-magnesium, mono-valent magnesium, and molecular calcium hydride complexes have been investigated to activate these polyphosphorus sources. The organo-magnesium complex ...


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