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The reaction behavior of [Cp2Mo2(CO)4(μ,η2:2-P2)] and [Cp′′Ta(CO)2(η4-P4)] towards hydroxide and tert-butyl nucleophiles

Riedlberger, Felix ; Seidl, Michael ; Scheer, Manfred


The reaction behavior of [Cp2Mo2(CO)(4)(mu,eta(2:2)-P-2)] (1) and [Cp '' Ta(CO)(2)(eta(4)-P-4)] (2), respectively, towards the anions OH- and Bu-t(-) are reported. While the reaction of 1 with KOH gives the anionic complex [Cp2Mo2(CO)(4)(mu-PH2)](-) (3) under a formal phosphorus atom abstraction, reaction with (LiBu)-Bu-t leads to the alkylation product [Cp2Mo2(CO)(4)(mu,eta(2:1)-(PPBu)-Bu-t)](-) ...


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