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Iron β-diiminate complexes with As2-, As4- and As8-ligands

Spitzer, Fabian ; Balázs, Gábor ; Graßl, Christian ; Scheer, Manfred


Different substituents at the beta -diiminato ligand in low-valent [LFe(tol)] (L = beta -diiminato) complexes fundamentally change their reactivity towards yellow arsenic. By using dmp (2,6-dimethylphenyl) as flanking groups, the tetranuclear complexes [(LFe)(4)As-8] (L = L-1 (1), L-2 (2)) are isolated. For dipp (2,6-diisopropylphenyl) substituted ligands, dinuclear complexes ...


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