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NMR Study of Intercalates and Grafted Organic Derivatives of H2La2Ti3O10

Shelyapina, Marina G. ; Silyukov, Oleg I. ; Lushpinskaia, Irina P. ; Kurnosenko, Sergey A. ; Mazur, Anton S. ; Shenderovich, Ilya G. ; Zvereva, Irina A.


The protonated perovskite-like titanate H2La2Ti3O10 has been used to produce organic-inorganic hybrids with simple organic molecules: methylamine, methanol, monoethanolamine, and n-butylamine. The optimal pathways for the preparation of such hybrids are summarized. Solid-state NMR, combined with thermal analysis, Raman, and IR spectroscopy, has been applied to determine the bonding type in the ...


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