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Synthesis and Characterization of a Novel Triangular Rh 2 Au Cluster Compound Inspired by the Isolobality Concept

Böttcher, Hans‐Christian ; Graf, Marion ; Mayer, Peter ; Scheer, Manfred



Zusammenfassung

The synthesis of [Rh-2(eta (5)-Cp)(2)(mu -H)(mu -PPh2)(2)]BF4 (2) by protonation reaction of the metal basic complex [Rh-2(eta (5)-Cp)(2)(mu -PPh2)(2)] (1) with tetrafluoroboric acid in diethyl ether is described. Complex salt 2 was obtained in high yield and fully characterized by spectroscopic means and X-ray crystal diffraction. Applying the isolobal analogy between H and the fragment Au(PPh3) ...

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