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Transformations of the cyclo-P4 ligand in [Cp′′′Co(η4-P4)]

Piesch, Martin ; Seidl, Michael ; Scheer, Manfred


The reactivity of thecyclo-P(4)ligand complex [Cp ''' Co(eta(4)-P-4)] (1) (Cp ''' = 1,2,4-tri-tert-butyl-cyclopentadienyl) towards reduction and main group nucleophiles was investigated. By using K[CpFe(CO)(2)], a selective reduction to the dianionic complex [(Cp ''' Co)(2)(mu,eta(3):eta(3)-P-8)](2-)(2) was achieved. The reaction of1with(t)BuLi and LiCH(2)SiMe(3)as carbon-based nucleophiles ...


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